Why can't explosion-proof lithium batteries be used in high-gas mines?

Introduction Why can't explosion-proof lithium batteries be used in high-gas mines? Why can't explosion-proof lithium batteries be used in high-gas mines? The reason why explosion-proof lithium batteries cannot be used in high gas mines

Why can't explosion-proof lithium batteries be used in high-gas mines?

Why can't explosion-proof lithium batteries be used in high-gas mines? The reasons why explosion-proof lithium batteries cannot be used in high-gas mines are:

1. Sparks and high temperatures: Lithium batteries will produce sparks during the charging and discharging process, which will cause the batteries to ignite. gas gas. Flammable gases such as methane can trigger an explosion when a lithium battery goes off.

2. Thermal Runaway: Overcharging, overdischarging and overheating lithium batteries will result in thermal runaway, further increasing the risk of mining accidents. Thermal runaway can cause combustion, explosion or release of toxic gases. . Lithium batteries are rechargeable batteries that use the movement of lithium ions between them.e positive and negative electrodes to store and release electrical energy.

Are lithium batteries more likely to explode

Are lithium batteries more likely to explode? Lithium batteries have been developed for more than several decades since their birth. market currently They also have built-in lithium batteries. We often see news about cell phone explosions, so is there a good chance that lithium batteries will explode? Let's find the answer together.

Are lithium batteries more likely to explode? 1

As long as it is a lithium battery, there is a risk of explosion, but the probability of this risk is very small. But once it explodes, the explosion power of a larger capacity lithium battery is unimaginable.

There are two important causes of explosionof a lithium battery, one is a short circuit and the other is an overcharge. A short circuit is easy to understand, that is, the positive and negative terminals of the battery are in direct contact. First, the heat generated by a short circuit in a small area over a normal short period of time is actually very small and will not cause thermal runaway. The battery core itself is designed with an explosion-proof valve, which means that when the internal pressure of the battery core exceeds a certain value, the explosion-proof valve will open and the heat will dissipate quickly. The second is that normally used battery charging equipment is protected against overload and stops charging when the battery voltage reaches a certain value. The third battery cell case itself is a very protective steel shell.

What is the powerwhat about the explosion of lithium batteries?

Calculate, a fully charged 2.6 Ah ternary 18650 lithium battery has a charge of 2.6* 3.65* 3 .6 = 34.164 kilojoules of energy. The energy generated when the muzzle of a general gun is fired is approximately 2.2 kilojoules, which is equivalent to the work done when a force of 1 Newton moves an object 1 meter in the direction of the force. meters from the gun, can easily kill enemies. Think about it, a Tesla requires more than 7,000 3.4 Ah 18650 model lithium batteries.

A 50AH battery with an aluminum alloy case and a size of 20*120*300 ( mm) and lithium manganate as a positive cell exploded during a load test: the 3 meter high roof was blackened. , a hole was dug in the wall about half a meter from the battery (I forget if the wall was brick or sandwich panel), and the door and window panes were shattered.Fortunately, there was no one there at the time of the explosion.

Lithium batteries therefore have a risk of fire, explosion and combustion, do not recharge, disassemble, crush, heat above 212°F or incinerate.

Causes of explosions and fires of lithium batteries

1. Insufficient capacity of the negative electrode of lithium batteries

When lithium When the capacity of the negative electrode of the positive electrode of the battery is insufficient, the lithium atoms generated during charging cannot be inserted into the graphite interlayer structure of the negative electrode and will precipitate on the surface of the negative. electrode to form crystals. Long-term crystal formation in lithium batteries will cause short circuits. At this time, the battery cells will discharge quickly, generating a large amount of heat and burningera the separators. High temperature will cause the electrolyte to decompose into gas. When the pressure is too high, the battery core will explode.

2. The water content is too high

During charging, water may react with lithium to generate lithium oxide , which will result in battery capacity. to be lost. It is easy to overcharge the battery core and generate gas. The decomposition voltage of water is low. It is easy to decompose to generate gas during charging. When this series of gases generated increases the internal pressure of the battery core. , the battery core shell cannot withstand it, the battery core will explode.

3. Internal short circuit

The internal short circuit of the cell causes a significant current discharge, generates a large amount of heat and burns the diaphragm. If a short circuitIf more happens, the electrolyte will decompose into gas and if the internal pressure is too high, the battery core will explode.

4. Overcharging of lithium batteries

When the battery is overcharged, excessive release of lithium from the positive electrode will cause the structure of the positive electrode. change, and the excess released lithium may easily not be inserted into the negative electrode and may easily cause lithium to precipitate on the surface of the negative electrode. Additionally, when the voltage reaches more than 4.5V, the electrolyte will decompose. produce a large amount of gas. All of the above can cause an explosion.

5. External short circuit

External short circuit can be caused by poor connection of positive and negative poles due to short circuit external. , the battery discharge current is very large, which will cause dbattery malfunction. The heat and high temperature of the core will cause the diaphragm inside the battery core to shrink or be completely damaged, causing an internal short circuit and thus an explosion.

Is there a high risk of a lithium battery exploding? 2

What is the risk of a ternary lithium battery exploding

The risk is quite high. When. the battery cell is overcharged, the positive electrode contains too much lithium. The release will change the structure of the positive electrode, and too much released lithium can easily not be inserted into the negative electrode, and it will also easily cause lithium precipitation. on the surface of the negative electrode. In addition, when the voltage exceeds 4.5 V, the electrolyte decomposes to produce a large amount of gas. All of the above can cause an explosion. The warning sign of an explosion is udoes not deform due to the heat generated during charging. The harmful consequences can be a short circuit, an open circuit or even an explosion.

Ternary lithium battery or 18650 lithium batteryWhich is more powerful in case of explosion

After all, the lithium battery is just a battery, not a bomb. Even though 18650 lithium battery is the worst in terms of safety, the discharge performance is also slow. At most, it burns violently after bursting. The so-called "explosion" only makes a little noise when it bursts. The final conclusion was that even if 2,000 to 3,000 lithium batteries were stacked together, the force of the explosion would still be limited and would hardly kill them. Therefore, in daily life, you should be careful when using equipment equipped with 18650 lithium batteries.

The process of pLithium battery repair is very successful. In addition to greatly improved performance, its security is also very comprehensive. In order to prevent the sealed metal case from exploding, a safety valve is installed on the top of the 18650 battery. This is the standard configuration of every 18650 battery and is also the most important explosion-proof barrier. When the internal pressure of the battery is too high, the safety valve on the top of the battery opens the exhaust and pressure reduction function to prevent explosion.

However, many issues remain regarding the safety of ternary lithium batteries. During a car accident, external impact may damage the battery diaphragm, causing a short circuit. The heat released during the short circuit will heat the battery and increase its temperature to over 300°C. Ternary lithium batterieshave poor thermal stability. Oxygen molecules decompose when the temperature is below 300°C. When exposed to the flammable electrolyte and carbonaceous materials of the battery, the heat generated further intensifies the decomposition of the positive electrode. shortly it will burn inside.

In comparison, another widely used lithium iron phosphate battery can be maintained at 700-800°C without decomposing oxygen molecules and is safer.

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