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SLOVENSKI STANDARD
01-april-2024
Nadomešča:
SIST-TS CEN/TS 17200:2019+AC:2019
Gradbeni proizvodi - Ocenjevanje sproščanja nevarnih snovi - Analiza
anorganskih snovi po razklopu in v izlužkih - Analiza z masno spektrometrijo z
induktivno sklopljeno plazmo (ICP-MS)
Construction products - Assessment of release of dangerous substances - Analysis of
inorganic substances in eluates and digests - Analysis by inductively coupled plasma
mass spectrometry (ICP-MS)
Bauprodukte - Bewertung der Freisetzung von gefährlichen Stoffen - Analyse von
anorganischen Stoffen in Aufschlusslösungen und Eluaten - Analyse mit induktiv
gekoppeltem Plasma - Massenspektrometrie (ICP-MS)
Produits de construction : Évaluation de l'émission de substances dangereuses -
Analyse des substances inorganiques dans les digestats et les éluats - Analyse par
spectrométrie de masse avec plasma à couplage inductif (ICP-MS)
Ta slovenski standard je istoveten z: EN 17200:2023
ICS:
13.020.99 Drugi standardi v zvezi z Other standards related to
varstvom okolja environmental protection
91.100.01 Gradbeni materiali na Construction materials in
splošno general
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
EN 17200
EUROPEAN STANDARD
NORME EUROPÉENNE
November 2023
EUROPÄISCHE NORM
ICS 91.100.01 Supersedes CEN/TS 17200:2018+AC:2018
English Version
Construction products: Assessment of release of
dangerous substances - Analysis of inorganic substances in
eluates and digests - Analysis by inductively coupled
plasma mass spectrometry (ICP-MS)
Produits de construction : Évaluation de l'émission de Bauprodukte: Bewertung der Freisetzung von
substances dangereuses - Analyse des substances gefährlichen Stoffen - Analyse von anorganischen
inorganiques dans les digestats et les éluats - Analyse Stoffen in Aufschlusslösungen und Eluaten - Analyse
par spectrométrie de masse avec plasma à couplage mit induktiv gekoppeltem Plasma -
inductif (ICP-MS) Massenspektrometrie (ICP-MS)
This European Standard was approved by CEN on 14 August 2023.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2023 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 17200:2023 E
worldwide for CEN national Members.
Contents Page
European foreword . 4
Introduction . 5
1 Scope . 6
2 Normative references . 6
3 Terms and definitions . 7
4 Abbreviations . 8
5 Principle . 9
6 Interferences . 9
6.1 General . 9
6.2 Spectral interferences . 9
6.2.1 Isobaric elemental interferences . 9
6.2.2 Isobaric molecular and doubly charged ion interferences . 9
6.3 Non-spectral interferences .10
7 Reagents .10
8 Apparatus .13
9 Procedure.14
9.1 Test sample .14
9.2 Test portion .14
9.3 Instrument set up .14
9.4 Calibration .15
9.4.1 Calibration function .15
9.4.2 Standard addition calibration .15
9.4.3 Determination of correction factors .15
9.4.4 Variable isotope ratio .15
9.5 Sample measurement .15
10 Calculation .16
10.1 Calculation for digests of construction products .16
10.2 Calculation for eluates of construction products .16
11 Expression of results .16
12 Performance characteristics .16
12.1 General .16
12.2 Blank .17
12.3 Calibration check .17
12.4 Internal standard response .17
12.5 Interference .17
12.6 Recovery .17
12.7 Indicative values for MDL .17
13 Test performance .17
14 Test report .18
Annex A (informative) Validation results for analysis of inorganic substances in eluates
and digests from construction products . 20
A.1 General . 20
A.2 Precision data for analysis of eluates from construction products . 20
A.3 Precision data for analysis of aqua regia digests from construction products . 27
Annex B (informative) Indicative values for MDL . 34
Bibliography . 35
European foreword
This document (EN 17200:2023) has been prepared by Technical Committee CEN/TC 351 “Construction
products: Assessment of release of dangerous substances”, the secretariat of which is held by NEN.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by May 2024, and conflicting national standards shall be
withdrawn at the latest by May 2024.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document supersedes CEN/TS 17200:2018+AC:2018.
In comparison with the previous edition, the following technical modifications have been made:
— the addition of performance data and data from intercomparison validation;
— alignment of terms and definitions within the working groups of CEN/TC 351, i.e. through the revised
version of EN 16687.
This document has been prepared under a Standardization Request given to CEN by the European
Commission and the European Free Trade Association.
Any feedback and questions on this document should be directed to the users’ national standards body.
A complete listing of these bodies can be found on the CEN website.
According to the CEN-CENELEC Internal Regulations, the national standards organisations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia,
Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland,
Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of North
Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and the United
Kingdom.
Introduction
Following an extended evaluation of available methods for content and eluate analysis in construction
products (CEN/TR 16045) it was concluded that multi element analysis methods have preference over
methods developed for single elements or small groups of elements. This implies that for inorganic
substances ICP methods are preferred for the analysis of extracts obtained from digestion or eluates
obtained from leaching.
This standard has been adopted from the work carried out in the context of CEN/TC 400 (project
HORIZONTAL) and is very similar to EN 16171.
The outcome of the analysis of materials that due to considerations of reuse/recycling could fall under
an evaluation as construction products would be considered to fall within the uncertainties as specified
by the respective methods and as such would not require an additional analysis, thus avoiding double
testing.
NOTE 1 A similar method has been validated for the determination of elements in aqua regia digests
(EN ISO 54321) for the following matrices: municipal sludge, industrial sludge, sludge from electronic industry, ink
waste sludge, sewage sludge, biowaste, compost, composted sludge, agricultural soil, sludge amended soil, waste,
city waste incineration fly ash (“oxidised” matrix), city waste incineration bottom ash (“silicate” matrix), ink waste
sludge (organic matrix), electronic industry sludge (“metallic” matrix), sewage sludge (BCR 146R), city waste
incineration ash (BCR 176).
NOTE 2 A similar method has been validated for the determination of elements in hydrochloric (HCl), nitric
(HNO ) and tetrafluoroboric (HBF ) or hydrofluoric (HF) acid mixture digests (EN 13656) for the following
3 4
matrices: city waste incineration ash (BCR176/BCR176R), ink waste sludge (organic matrix), electronic industry
sludge (“metallic” matrix), sediment, coal fly ash, steel slag, copper slag, city waste incineration fly ash (“oxidised”
matrix), city waste incineration bottom ash (“silicate” matrix), sewage sludge (BCR 146R).
This document is part of a modular horizontal approach which was adopted in CEN/TC 351. “Horizontal”
...